A novel one-dimensional cyano-bridged Ni3Fe2 ferromagnet constructed from bimetallic molecular squares.

نویسندگان

  • Enrique Colacio
  • José M Domínguez-Vera
  • Francesc Lloret
  • Antonio Rodríguez
  • Helen Stoeckli-Evans
چکیده

Reaction of the complex [Ni(rac-CTH)](2+) (rac-CTH = rac-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) with [Fe(CN)(6)](3-) leads to a novel cyano-bridged Ni(3)Fe(2) complex, [[Ni(rac-CTH)](3)[Fe(CN)(6)](2)](4). The structure consists of an alternating arrangement of [Fe(CN)(6)Ni(rac-CTH)](2) squares and trans-planar [Ni(rac-CTH)](2+) units bridged by cyanide groups to give a neutral 1D chain running along the a axis. Magnetic measurements reveal the occurrence of ferromagnetic coupling between Fe(III) and Ni(II) ions and 3D magnetic ordering at 3 K due to interchain interactions. Canting of the moments is inferred from the low value of the magnetization of the saturation below T(c).

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عنوان ژورنال:
  • Inorganic chemistry

دوره 42 22  شماره 

صفحات  -

تاریخ انتشار 2003